Metal-organic frameworks (MOFs) and their composites as electrodes for lithium battery applications: Novel means for alternative energy storage ...

Metal-organic frameworks (MOFs) and their composites as electrodes for lithium battery applications: Novel means for alternative energy storage Author links open overlay panel Vishal Shrivastav a b 1, Shashank Sundriyal a b 1, Priyanshu Goel a b, Harmeet Kaur a b, Satish K. Tuteja c, Kumar Vikrant d, Ki-Hyun Kim d, Umesh K. …

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Recent Progress and Design Principles for Rechargeable Lithium …

By classifying Li-storage mechanisms with various functional organic groups and designing molecules for next-generation advanced lithium organic systems, we attempt …

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High-Energy All-Solid-State Organic–Lithium Batteries Based on Ceramic Electrolytes | ACS Energy …

Recent studies have identified unique properties of organic battery electrode materials such as moderate redox potentials and mechanical softness which are uniquely beneficial for all-solid-state batteries based on ceramic electrolytes. Here, we further explore the promise of organic materials and demonstrate a sulfide electrolyte …

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Lithium-Ion Battery

Li-ion batteries have no memory effect, a detrimental process where repeated partial discharge/charge cycles can cause a battery to ''remember'' a lower capacity. Li-ion batteries also have a low self-discharge rate of around 1.5–2% per month, and do not contain toxic lead or cadmium. High energy densities and long lifespans have made Li ...

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Organic batteries for a greener rechargeable world

Organic rechargeable batteries have emerged as a promising alternative for sustainable energy storage as they exploit transition-metal-free active materials, …

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Opportunities and Challenges for Organic Electrodes in …

A Unified Charge Storage Mechanism to Rationalize the Electrochemical Behavior of Quinone-Based Organic Electrodes in Aqueous Rechargeable Batteries. …

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2D Metal–Organic Frameworks for Electrochemical Energy Storage

Lithium-sulfur batteries are popular candidates for high-energy rechargeable batteries due to the merits of environmental friendliness, theoretical energy density of up to 2600 Wh kg −1, ultra-high theoretical capacity (1675 mAh g −1), and relatively low price.

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High-performance lithium–organic batteries by …

Organic materials have attracted intensive research interest in lithium ion batteries (LIBs) ... (DFT) calculations, the Li storage mechanism of PIAQ is a reversible process associated with a six-step …

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Opportunities and Challenges for Organic Electrodes in Electrochemical Energy Storage …

Insight into Chemical Reduction and Charge Storage Mechanism of 2,2′-Dipyridyl Disulfide toward Stable Lithium–Organic Battery. The Journal of Physical Chemistry Letters 2021, 12 (2), 900-906.

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A Unified Charge Storage Mechanism to Rationalize the Electrochemical Behavior of Quinone-Based Organic Electrodes in Aqueous Rechargeable Batteries

Due to their eco-sustainability and versatility, organic electrodes are promising candidates for large-scale energy storage in rechargeable aqueous batteries. This is notably the case of aqueous hybrid batteries that pair the low voltage of a zinc anode with the high voltage of a quinone-based (or analogue of quinone-based) organic …

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Sustainable Energy Storage: Recent Trends and Developments toward Fully Organic Batteries …

In times of spreading mobile devices, organic batteries represent a promising approach to replace the well-established lithium-ion technology to fulfill the growing demand for small, flexible, safe, as well as sustainable energy storage solutions. In the last years, large ...

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Outstanding Lithium Storage Performance of a …

The preliminary lithium storage mechanism is analyzed on the basis of FT-IR, XPS, EPR characterization and electrochemical analysis. This study enlightens a novel method to …

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Design strategies and energy storage mechanisms of MOF-based aqueous zinc ion battery …

For MOFs, which have both organic and inorganic properties, their energy storage mechanisms are more ambiguous. Here, we summarize the results of numerous researchers on the energy storage mechanisms of pristine MOF cathode materials at this stage, and propose two predominant energy storage mechanisms that cover the …

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Lithium Storage Mechanism: A Review of Perylene Diimide N-Substituted with a 1,2,4-Triazol-3-yl Ring for Organic …

The demand for lithium-ion batteries (LIBs) has increased rapidly. However, commercial inorganic-based cathode materials have a low theoretical capacity and inherent disadvantages, such as high cost and toxicity. Redox-active organic cathodes with a high theoretical capacity, eco-friendly properties, and sustainability have been developed to …

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Outstanding Lithium Storage Performance of a Copper‐Coordinated Metal‐Covalent Organic Framework as Anode Material for Lithium‐Ion Batteries ...

1 Introduction In view of the high-energy density and long-term cycling stability, lithium-ion batteries (LIBs) are outstanding in varieties of energy storage devices. [1-5] However, the demand for advanced LIBs is ever-increasing to high …

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Charge Storage Mechanism of an Anthraquinone …

Therefore, a combined charge storage mechanism including multiredox processes and an ions absorption/desorption process is proposed for the DAAQ-COF. This work deepens the understanding of …

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Rechargeable Organic Batteries: Materials, Mechanisms, and …

<p><b>A must-have reference on sustainable organic energy storage systems</b> <p>Organic electrode materials have the potential to overcome the intrinsic limitations of transition metal oxides as cathodes in rechargeable batteries. As promising alternatives to metal-based batteries, organic batteries are renewable, low-cost, and would enable a …

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Towards practical organic batteries | Nature Materials

This could provide a new platform for the Li-ion battery community to design organic electrode materials for eco-friendly and sustainable energy storage and …

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Polypeptide organic radical batteries | Nature

Organic radical batteries promise increased environmental friendliness, independence from strategic metals and faster charging rates compared to lithium-ion batteries 3,4,9,10,11,12,13,14.

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Sulfur‐containing polymer cathode materials: From energy storage mechanism to energy …

1 INTRODUCTION Lithium-ion batteries (LIBs) are one of most promising energy storage device that has been widely used in mobile phones, portable electronics, and electric vehicles in past two decades. 1-4 As our economy and technology advance, LIBs have reached the ceiling of their performance (< 250 mAh g −1) and could not meet …

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Industrial-scale synthesis and application of covalent organic frameworks in lithium battery …

Covalent organic frameworks (COFs) have emerged as a promising strategy for developing advanced energy storage materials for lithium batteries. Currently commercialized materials used in lithium batteries, such as graphite and metal oxide-based electrodes, have shortcomings that limit their performance and reliability.

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Exploring metal organic frameworks for energy storage in batteries and supercapacitors …

The clear mechanism of the MOF-derived oxides/sulfides for Li-Se batteries should be further developed and thoroughly understood. The above studies on Li-O 2 batteries, Li-S batteries, and Li-Se batteries show …

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By classifying Li-storage mechanisms with various functional organic groups and designing molecules for next-generation advanced lithium organic systems, …

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Electrochemical Performance and Mechanism of …

The abundance of Ca, its low redox potential and high specific capacity make Ca metal batteries an attractive energy storage system for the future. A recent demonstration of room temperature …

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Anion Storage Chemistry of Organic Cathodes for High-Energy and High-Power Density Divalent Metal Batteries …

Introduction Growing demand for electric vehicles and the implementation of intermittent renewable energies have stimulated the research interests in exploring sustainable, high-energy, high-power electrochemical storage systems. 1 Rechargeable Mg and Ca batteries are expected to provide efficient, safe, cost-effective battery solutions …

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Insight into Chemical Reduction and Charge Storage Mechanism of 2,2''-Dipyridyl Disulfide toward Stable Lithium-Organic Battery

In lithium-organic batteries, organic cathode materials could dissolve in a liquid electrolyte and diffuse through the porous separator to the active lithium-metal anode, resulting in cycling instability. However, 2,2''-dipyridyl disulfide (PyDS) can be cycled 5 times better than diphenyl disulfide ( …

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Charge Storage Mechanism of an Anthraquinone-Derived Porous Covalent Organic Framework with Multiredox Sites as Anode Material for Lithium-Ion Battery

Design and construction of high-capacity covalent organic frameworks (COFs)-based electrode materials and research on the energy storage mechanism still present challenges. In this study, an anthraquinone-derived porous covalent organic framework (DAAQ-COF) with dual-redox active sites of C═N and C═O groups is …

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Energy storage mechanisms of anode materials for potassium ion batteries …

The applications of potassium ion batteries (KIBs) require the development of advanced electrode materials. The rate performance and cycle stability of anode materials are critical parameters and are closely related to their K+ storage mechanisms and structural changes during cycling. This review presents an overview of the …

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Direct regeneration of degraded lithium-ion battery cathodes with a multifunctional organic lithium …

LiFePO4 batteries have been widely used in electric vehicles and energy storage stations. Currently, lithium loss ... sources and pathways of spent lithium-ion batteries. Energy Environ. Sci. 14 ...

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Boosting lithium storage in covalent organic framework via …

Aided by theoretical calculations and electrochemical probing of the electrochemical behavior at different stages of cycling, the storage mechanism is …

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Charge Storage Mechanism and Structural Evolution of Viologen Crystals as the Cathode of Lithium Batteries …

The EVI 2 electrode exhibits a high initial discharge plateau of 3.7 V (vs. Li + /Li) because of its anion storage ability. When I − is replaced by ClO 4 −, the obtained EV(ClO 4 ) 2 electrode displays excellent rate performance with a theoretical capacity of 78 % even at 5 C owing to the good electron conductivity of ClO 4 − layers.

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